AQA GCSE Chemistry contents

Unit 7 · Organic Chemistry

Crude Oil, Hydrocarbons & Alkanes

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Crude oil

  • Crude oil is a finite resource found in rocks. It is the remains of ancient biomass, mainly plankton, buried in mud and compressed over millions of years
  • It is a mixture of a very large number of compounds, most of them hydrocarbons: molecules made of hydrogen and carbon atoms only
  • Because it is a mixture it can be separated by a physical process, fractional distillation

Alkanes

  • Most of the hydrocarbons in crude oil are alkanes
  • Alkanes are a homologous series: a family of compounds with the same general formula and similar chemical properties, each member differing by CH2\text{CH}_2
  • General formula: CnH2n+2\text{C}_n\text{H}_{2n+2}
  • Alkanes are saturated: every carbon–carbon bond is a single bond, so each carbon has four single bonds in total
Alkane Formula Displayed formula
Methane CH4\text{CH}_4 one carbon, four hydrogens
Ethane C2H6\text{C}_2\text{H}_6 two carbons joined, six hydrogens
Propane C3H8\text{C}_3\text{H}_8 three carbons in a chain, eight hydrogens
Butane C4H10\text{C}_4\text{H}_{10} four carbons in a chain, ten hydrogens

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formulae of the first four alkanesGeneral formula CₙH₂ₙ₊₂ — every bond is a single bond, and every carbon has four of them.CHHHHmethane CH₄CHHHCHHHethane C₂H₆CHHHCHHCHHHpropane C₃H₈CHHHCHHCHHCHHHbutane C₄H₁₀Alkanes are saturated — they contain only single bonds. As the chains get longer the moleculeshave higher boiling points, are more viscous and are less flammable.
Displayed formulae of methane, ethane, propane and butane, every bond drawn as a line

  • To recognise an alkane from its formula, check that the hydrogens are 2n+22n + 2: C8H18\text{C}_8\text{H}_{18} is an alkane, C8H16\text{C}_8\text{H}_{16} is not